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The 307 is not sold anymore new, it would be second-hand 
It is still sold, the 307 hatchback, the one that Neptune likes is still available in Spain and Italy, not in Belgium, France, Germany or the United Kingdom apparently, only the cabrio and the Station Wagon versions are available in a few countries.
#2 Once settled, I would make a beeline to the nearest Peugeot dealership and purchase a 307. Or maybe a 1007 (I know its sort of like a minivan, but it looks neat with the two sliding main access doors) It doesn’t look like a traditional American minivan, which I like.
Neptune the 1007 is too far from being a minivan! its just a small two seater hatchback with sliding doors, not much you can do with it, and depending in where city you would stay you could perhaps keep your Expedition and leave pedestrians like
if you'd go to a city like Madrid or Barcelona with its big avenues you wouldnt have a problem